| 2009 |
Cooperative self-assembly assisted formation
of monodipserse optically active spherical and
anisotropic nanoparticles

This article
summarizes the recent
advances in the synthesis and
self-assembly of a new building block:
nanocrystal-micelle. Its bioapplications
and formation of ordered arrays for
integrationof charge transport devices
are also discussed.



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"Pressure-induced phase transformation of spherical nanoparticle assemblies into highly ordered nanowire arrays,"
H. Wu, F. Bai, Z. Sun, R. E. Haddad, D. M. Boye, Z. Wang, and H. Fan
Submitted.
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"Hydrogen-bonding-assisted self-assembly: monodisperse hollow nanoparticles made easy,"
Z. Sun, F. Bai, H. Wu, S. K. Schmitt, D. M. Boye, and H. Fan
Journal of the American Chemical
Society,131 (38), pp 13594 – 13595, 2009. Online

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"Cooperative self-assembly assisted formation of monodipserse optically active spherical and anisotropic nanoparticles,
Z. Sun, F. Bai, H. Wu, S. K. Schmitt, D. M. Boye, Z. Jiang, J. Wang, and H. Fan
Chemistry - A European Journal, 15, 11128 – 11133, 2009. Online

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"Vapor sensing using
conjugated molecule-linked Au nanoparticles in a silica matrix,"
S. M. Dirk, S. W. Howell, B. K. Price, H. Fan, C.
Washburn, D. R. Wheeler, J. M. Tour, J. Whiting, and R. J. Simonson
Journal of Nanomaterials, 2009.

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2008
- "Dynamic investigation of gold nanocrystal
assemby using in-situ
grazing-incidence small-angle x-ray,"
D. Dunphy, X. Li, J. Wang, C. J.
Brinker, and H. Fan,
Langmuir, 24 (19) 10575-10578, 2008. [pdf]
- "Lithographically Defined Carbon Growth
Templates for ELOG of GaN,"
D. B. Burckel, H. Fan, G.
Thaler, and D. D. Koleske,
Journal of Crystal Growth, 310 (12), 3113-3116,
2008.
- "Nanocrystal-micelles: synthesis,
self-assembly, and applications,"
H. Fan,
Chemical Communications, 12,
1383-1394, 2008. (invited feature article, cover, Chem Comm's top 5 from 2008)
- "An NBD fluorophore-based sensitive and
selective
fluorescent probes for zinc ion,"
W. Jiang, Q. Fu, H. Fan, W. Wang,
Chemical Communications, 2 , 259-261,
2008. |
2007
- "Facile synthesis of nanostructured carbon
through self-assembly
between block copolymers and carbohydrates,"
A. T. Rodriguez, X.
Li, J. Wang, W. A. Steen, and H. Fan,
Advanced
Functional Materials, 15,
2710-2716, 2007. [pdf]
- "A highly selective fluorescent probe for
thiophenols,"
W. Jiang, Q. Fu, H. Fan, J. Ho,
W. Wang,
Angew. Chem. Int. Ed. 46, 8445-8448, 2007.
- "Synthesis
and self-assembly of fcc
phase FePt Nanorods,"
M. Chen, T. Pica, T-B Jiang, P. Li, K. Yano, J. P. Liu, A. K. Datye,
and H. Fan,
Journal of the American Chemical
Society, 129 (20),
6348-6349, 2007. [pdf]
- "Modulus-density scaling behaviour
and framework architechture of nanoporous self-assembled silicas,"
H. Fan, C.
Hartshorn, T. Buchheit, D. Tallant, R. Assink, R.
Simpson, D. Kissel, D. J. Lacks, S. Torquato, and C.
J. Brinker,
Nature Materials, 6, 418-423, 2007. |
2006
- "Convective self-assembly to
synthesize supported ultra-thin mesoporous
silica films,"
Zhen Yuan, Bruce Burckel, Plamen
Atanassov, and Hongyou Fan,
Journal
of Materials Chemistry, 16 (48), 4637-4641,
2006. (featured
on cover) [pdf]
- "Synthesis of FePt nanocubes
and their oriented self-assembly,"
Min
Chen, Jaemin Kim, J, P. Liu, Hongyou Fan, and Shouheng Sun,
Journal of the American
Chemical Society, 128
(22), 7132 -7133, 2006.
- "Nanoporous carbon nanotubes
synthesized through confined hydrogen
bonding self-assembly,"
Adrian T. Rodriguez, Min Chen,
and Zhu Chen, Jeffrey
Brinker, and Hongyou Fan,
Journal of the American
Chemical Society, 128
(29), 9276-9277, 2006. [pdf]
- "Hierarchical ordered
mesophase crystals formed through hydrothermal
self-assembly of nanocrystal-micelles and silsesquioxane,"
Adam Wright, John
Gabaldon, Bruce Burckel, Ying-Bing Jiang, Z Ryan Tian, Jun Liu, Jeffrey
Brinker, and Hongyou Fan,
Chemistry of
Materials, 18(13), 3034-3038, 2006. (Featured
on Cover from September to October 2006)
[pdf]
- "Cell-directed
assembly of the bio-nano interface,"
Helen K. Baca, Carlee Ashley,
Eric Carnes,
Deanna Lopez, Jeb Flemming, Darren Dunphy, Seema Singh, Zhu Che, Nanguo
Liu,
Hongyou Fan, Gabriel P. Lopez, Susan M. Brozik, Margaret
Werner-Washburne,
and
C. Jeffrey Brinker,
Science, 313 (no. 5785), 337-341, 2006. (Featured on C & E News 2006)
- "Ordered nanocrystal/silica
particles self-assembled from nanocrystal micelles and silicate,"
Hongyou Fan, John Gabaldon, C.
Jeffrey Brinker, and Ying-Bing Jiang,
Chemical
Communications, 22,
2323-2325, 2006. (Featured on Cover) [pdf]
- "3-Dimensionally ordered gold
nanocrystal/silica superlattice thin films synthesized via sol-gel
self-assembly,"
Hongyou Fan, Adam, Wright, John
Gabaldon, Adrian Rodriguez, Jeffrey Brinker, and Ying-Bing Jiang,
Advanced
Functional Materials, vol. 16, 891-895, 2006. (Featured
on Cover) [pdf] |
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2005
- "Synthesis of
organo-silane functionalized nanocrystal micelles and their
self-assembly,"
Hongyou Fan, Zhu Chen, Jeffrey Brinker, Jacalyn
Clawson, and Todd Alam,
Journal of the American
Chemical Society vol.127, 13746-13747, 2005. [pdf]
- "Ordered two- and
three-dimensional arrays self-assembled from water-soluble
nanocrystal-micelles,"
Hongyou Fan, Erik Leve, John Gabaldon, Adam Wright,
Raid E. Haddad, Jeffrey Brinker,
Advanced Materials vol.17, 2587-2590, 2005. [pdf]
- "Electrical and optical properties of self-assembled, ordered
gold nanocrystal/silica thin films prepared by sol-gel processing,"
Kai Yang, Hongyou Fan, Kevin J.
Malloy, C. Jeffrey Brinker, and Thomas W. Sigmon,
Mater. Res. Soc.
Symp. Proc., vol. 872,
103-108, 2005.
- "Surfactant-assisted synthesis of water-soluble and
biocompatible quantum dot micelles for bioapplications,"
Hongyou Fan,
Erik W. Leve, Chessa Scullin, David Tallant, Michael C. Wilson, C. J.
Brinker,
Proc.
SPIE, Vol. 5705,
92-100, 2005.
- "Optical and electrical
properties of self-assembled, ordered gold nanocrystal/silica thin
films prepared by sol-gel processing,"
Kai Yang, Hongyou Fan, Kevin J. Malloy, C. Jeffrey
Brinker, and Thomas W. Sigmon,
Thin Solid Film vol. 491, 38-42, 2005.
- "Surfactant-assisted
synthesis of water-soluble and biocompatible quantum dot
micelles,"
Hongyou Fan, Erik W. Leve, Chessa Scullin, John
Gabaldon, David Tallant, Scott Bunge, Tim Boyle, Michael C. Wilson, and
C. Jeffrey Brinker,
Nano Letters
vol. 5, 645-648, 2005. (One of the most highly accessed articles on ACS
website) [pdf] |
|
2004
- "Self-assembly
of ordered, robust, three-dimensional gold/silica nanocrystal
arrays,"
Hongyou Fan, Kai Yang, Daniel M.
Boye, Thomas Sigmon, Kevin J. Malloy, Huifang Xu, and C. Jeffrey
Brinker,
Science vol.304, 567-571, 2004. [pdf]
- "Evaporation-induced self-assembly to
functional nanostructure,"
Hongyou Fan and Jeffrey Brinker,
Studies in Surface
Science and Catalysis, vo1. 48, 213-240, 2004. |
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Publications before 2003
- "Investigation of
templated mesoporous silicate materials using high speed, solid-state 1H
MAS and double quantum NMR spectroscopy."
Todd M. Alam and
Hongyou Fan,
Macromolecular
Chemistry and Physics vol. 204, No.16, 2023-2030, 2003.
- "Characterization of the microstructure of
PS-b-PEO-templated silica films with a 3-D
arrangement of spherical mesopores,"
Bernd Smarsly, Kui Yu, George,
Xomeritakis, Roger A. Assink, Celeste Drewien, Nanguo Liu, Hongyou Fan,
Wilhelm Ruland, C. Jeffrey Brinker,
Langmuir vol.19, no.18,
7295-7301, 2003.
- "Synthesis and characteization of a novel
family of lithium cobalt double alkoxides and the characterization of
the nanoparticle and thin films generated there from,"
Timothy J. Boyle, Mark A.
Rodriguez, David Ingersoll, Dawn M. Pedrotty, Sara C. Vick, Scott D.
Bunge. Hongyou Fan,
Chemistry of
Materials vol. 15, 3903-3912, 2003.
- "Functional nanocomposites prepared by
self-assembly and polymerization of diacetylene surfactants and silicic
acid,"
Yi Yang, Yunfeng Lu, Mengcheng
Lu, Jinman Huang, Raid Haddad, George Xomeritakis, Nanguo Liu, Anthony
P. Malanoski, Dietmar Sturmayr,
Hongyou Fan, Darryl Y.
Sasaki, Roger A. Assink, John A. Shelnutt, Frank van Swol, Gabriel P.
Lopez, Alan R. Burns, and C. Jeffrey Brinker,
Journal of the American Chemical
Society vol. 125, 1269-1277, 2003.
2001
- "Self-assembled aerogel-like low
dielectric constant films,"
Hongyou Fan, Holly R. Bentley, Kyle R. Kathan, Paul Clem, Yunfeng Lu,
and C. Jeffrey Brinker,
Journal of
Non-Crystal. Solids vol. 285 (#1-3) 79-83, 2001.
- "Multiphased assembly of nanoporous silica
particles,"
Hongyou Fan, Frank Van Swol,
Yunfeng Lu, and C. Jeffrey Brinker,
Journal of
Non-Crystal. Solids vol. 285 (#1-3), 71-78, 2001.
- "Hierarchically structured functional
porous and composite mesostructures produced by evaporation-driven
self-assembly,"
Hongyou Fan, Scott T. Reed, Tom
Baer, Randy Schunk, Gabriel P. Lopez, and C. Jeffrey Brinker,
Microporous
and Mesoporous Materials vol. 44-45, 625-637, 2001.
- "Self-assembly of mesoscopically ordered
chromatic polydiacetylene/silica nanocomposites,"
Yunfeng Lu, Yi Yang, Alan
Sellinger, Mengcheng Lu, Jinman Huang, Hongyou Fan, Raid Haddad,
Gabriel P. Lopez, Alan R. Burns, Darryl Y. Sasaki,
John Shelnutt,
and C. Jeffrey Brinker,
Nature, vol.
410, 913-917, 2001.
2000
- "Rapid prototyping of patterned functional
nanostructures,"
Hongyou Fan, Yunfeng Lu, Aaron
Stump, Scott T. Reed, Tom Baer, Randy Schunk, Victor Perez-Luna,
Gabriel P. Lopez, and C. Jeffrey Brinker,
Nature, vol.
405, 56-60, 2000.
- "Surfactant
templated mesoporous hybrid thin films," Hongyou Fan, Yunfeng Lu, Roger
A. Assink, Gabriel P. Lopez, and C. Jeffrey Brinker, Mat. Res. Soc.
Symp. Proc., vol. 628, CC6.41.1-CC6.41.7, 2000.
- "Patterned
Functional Arrays by Selective De-wetting," Hongyou Fan, Dhaval D.
Doshi, Yunfeng Lu, Gabriel P. Lopez, and C. Jeffrey Brinker, Mat.
Res. Soc. Symp. Proc., vol. 628, CC6.33.1-CC6.33.6, 2000.
- "Rapid
Prototyping of Patterned Multifunctional Nanostructures," Hongyou Fan,
Gabriel P. Lopez, and C. Jeffrey Brinker, Mat. Res. Soc. Symp. Proc.,
vol. 624, 231-240, 2000.
- "Optically,
defined multifunctional patterning of photosensitive thin-film silica
mesophases," Dhaval Doshi, Nicola Huesing, Mencheng Lu, Hongyou Fan,
Yunfeng Lu, Simmons Potter K, Potter BG,
Alan A. Hurd, and C. Jeffrey Brinker, Science,
vol. 290,107-111, 2000.
- "Evaporation-induced
self-assembly of hybrid bridged silsesquioxane film and particulate
mesophases with integral organic functionality," Yunfeng Lu, Hongyou
Fan, Nilesh Doke, Douglas A. Loy,
Roger A. Assink, David A. Lavan, and C.
Jeffrey Brinker, Journal of the American Chemical Society vol.
122, 5258-5261, 2000.
- "A new
application of UV-ozone treatment in the preparation of
substrate-supported mesoporous thin films," Theotis Clark, Jr., Julia
D. Ruiz, Hongyou Fan, C. Jeffrey Brinker, Basil I. Swanson,
and Atul N. Parikh, Chemistry of
Materials vol. 12, 3879-3884, 2000.
1999
- "Aerosol-assisted
self-assembly of mesotructured spherical nanoparticles," Yunfeng Lu,
Hongyou Fan, Aaron Stump, Timothy, L. Ward, Thomas Rieker, and C.
Jeffrey Brinker, Nature vol. 398, 223 – 226, 1999.
- "Evaporation-induced
self-assembly: nanostructures made easy," C. Jeffrey Brinker, Yunfeng,
Lu, Alan Sellinger, and Hongyou Fan, Advanced Materials vol.
11, No. 7, 579-585, 1999.
- "Nanostructural
lithography via photo-initiated phase transition of silica-surfactant
assemblies," Dhaval Doshi, Nicola Huesing, Hongyou Fan, Alan A. Hurd,
and C. Jeffrey Brinker, Mat. Res. Soc. Symp. Proc., vol. 576,
263-268, 1999.
1998
- "Compositional-mapping
of micropatterned, mixed self-assembled monolayers by lateral force
microscopy," Yuqing Zhou, Hongyou Fan, Tommy Fong, and Gabriel P.
Lopez, Langmuir vol. 14 (#3), 660-666, 1998.
1997
- "Adsorption
of surface-modified colloidal gold particles onto self-assembled
monolayers: A model system for the study of interactions of colloidal
particles and organic surfaces," Hongyou Fan and Gabriel P. Lopez, Langmuir,
vol. 13(#2) 119-121, 1997.
- "Stepwise
assembly in three dimensions: Preparation and characterization of
layered gold nanoparticles in porous silica matrices," Hongyou Fan,
Yuqing Zhou, and Gabriel P. Lopez, Advanced Materials vol. 9
(#9), 728-731, 1997.
1996
- "Attachment
of bacteria to model solid surfaces: Oligo(ethylene glycol) surfaces
inhibit bacterial attachment," Linnea K. Ista, Hongyou Fan, Oswald
Baca, and Gabriel P. Lopez, FEMS Microbiology Letters vol.142
(#1), 59-63, 1996.
- "Electrochemical
patterning of self-assembled monolayers onto microscopic arrays of gold
electrodes fabricated by laser ablation," Lenny M. Tender, Lewis L.
Worley, Hongyou Fan, and Gabriel P. Lopez, Langmuir vol. 12
(#23) 5515-5518, 1996.
1994
"Ion beam
effects on polyaniline films," Lin, Senhao; Rong, Tingwen; Wan, Honghe;
Bao, Jinrong; Wang, Wenmin; Sun, Jianhua; Jing, Xiabing; Wang, Lixiang;
Fan, Hongyou, Acta Polymerica Sinica vol. 1, 48-54,
1994. |
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