Research Publications (1976-1990):  

1. Nucleoside Phosphorothioates: I. Thiophosphorylation of Nucleosides with Phosphorus Thioxy-anions. D. Dunaway-Mariano*, Tetrahedron 32: 2991-29996 (1976).

2. The Chemistry of Azocines. Intermediates for the Synthesis of Pyrrolizidines. P. S. Mariano*, M. E. Osborn, D. Dunaway-Mariano, B. C. Gunn and R. C. Pettersen, J. Organic Chem. 42: 2903-2910 (1977).

3. 7,8-Dicarbomethoxy-9-oxa-2-azabicyclo(4.2.1)non-7-ene-2-p-Toluene Sulfonamide. R. C. Pettersen*, P.S. Mariano*, M. E. Osborn and D. Dunaway-Mariano, Cryst. Struct. Comm. 6: 471-476 (1977).

4. Novel Approaches to the Synthesis of Hydroisoquinolines Using Aza-Claisen Rearrangements of N-Vinylisoquniuclidenes. P. S. Mariano*, D. Dunaway-Mariano, P. L. Huesmann and R. L. Beamer, Tetrahedron Lett., 4299-5209 (1977).

5. General Synthetic Methods for the Preparation of 1-Substituted-Vinyl-2-Pyridones. P. S. Mariano*, E. Krochmal, R. Beamer, P. L. Husemann and D. Dunaway-Mariano, Tetrahedron 34: 2609-2616 (1978).

6. The Diels-Adler Chemistry 1-Vinyl-2-Pyrodones. P. S. Mariano*, P. S. Huesmann, R. L. Beamer and D. Dunaway-Mariano, Tetrahedron 34: 2617-2626 (1978).

7. Specificity of Nucleoside Transport in Neurospora crassa. D. Dunaway-Mariano* and J. M. Magill, J. Bacteriol. 136: 924-928 (1978).

8. Amino-Claisen Rearrangements of N-Vinylisoquinuclidenes in Novel Approaches to the Synthesis of Hydroisoquinolines and Hydrophenanthridines. P. S. Mariano*, D. Dunaway-Mariano and P. L. Huesmann, J. Org. Chem. 44: 124-133 (1979).

9. Stereospecificity of the Metal-ATP Complex in Reactions of Pyruvate Kinase. D. Dunaway-Mariano, J. Benovic, W. W. Cleland*, R. K. Gupta and A. S. Mildvan*, Biochemistry 18: 4347-4354 (1979).

10. Preparation and Properties of Chromium(III) Adenosine 5'-triphosphate, Chromium(III) Adenosine 5'-diphosphate and Related Chromium(III) Complexes, D. Dunaway-Mariano and W. W. Cleland*, Biochemistry 19:1496-1505 (1980).

11. Investigations of Substrate Specificity and Reaction Mechanisms of Several Kinases Using Chromium(III) Adenosine 5'-triphosphate and Chromium(III)5'-diphosphate. D. Dunaway-Mariano and W. W. Cleland*, Biochemistry 19:1507-1515 (1980).

12. Crystal Structure and Chelate Ring Pucker of Bidentate Pyrophosphatotetra-aqua-chromium(III) Trihydrate, a Model for Metal-ADP Coordination. E. A. Merrit, M. Sundaralingam* and D. Dunaway-Mariano*, J. Amer. Chem. Soc. 103: 3565-3567 (1981).

13. Investigation of the Mechanism of Yeast Inorganic Pyrophosphatase. W. B. Knight, S. W. Fitts and D. Dunaway-Mariano*, Biochemistry 20: 4079-4086 (1981).

14. X-Ray Crystallographic and Nuclear Magnetic Resonance Spectral Studies of the Products from the Yeast Inorganic Pyrophosphatase-Co(NH3)4PP Reaction. Investigation of the Pyrophosphatase Reaction Mechanism. T. P. Haromy, W. B. Knight, D. Dunaway-Mariano* and M. Sundaralingam*, Biochemistry 21: 6950-6956 (1982).

15. Yeast Inorganic Pyrophosphatase Substrate Recognition. W. B. Knight, S.-J. Ting, S. Chuang, D. Dunaway-Mariano*, T. P. Haromy and M. Sundaralingam, Archives of Biochemistry & Biophysics 227: 302-309 (1983).

16. Investigation of the Structure, Protonation and Reactivity of Tetraamine(imidodi-phosphato)cobalt(III), A Substrate for Potato Apyrase. T. P.Haromy, W. B. Knight, D. Dunaway-Mariano* and M. Sundaralingam, Biochemistry 22: 5015-5121 (1983).

17. An Examination of the Solvent Perturbation Techniques as a Method to Identify Enzyme Catalytic Groups. S. Grace and D. Dunaway-Mariano*, Biochemistry 22: 4238-4247 (1983).

18. Phosphoryl Group Activation in the Yeast Inorganic Pyrophosphatase Reaction. Su-Jen Ting and D. Dunaway-Mariano*, FEBS Lett. 165: 251-253 (1984).

19. The Preparation and Characterization of Rh(III) Polyphosphate Complexes. I. Lin, W. B. Knight, S.-J. Ting and D. Dunaway-Mariano*, Inorganic Chemistry 23: 988-991 (1984).

20. Investigations of the Metal Ion Binding Sites of Yeast Inorganic Pyrophosphatase. W. B. Knight, D. Dunaway-Mariano*, S. Ransom and J. J. Villafranca*, J. Biol. Chem. 259: 2886-2895 (1984).

21. Crystal Structure of Bidentate Tetraamine(pyrophosphato)chromium(III)Dihydrate, Cr(H3)4HP2O7.2H20. T. P. Haromy, W. B. Knight, D. Dunaway-Mariano* and M. Sundaralingam*, Acta Crystallography C40: 223 (1984).

22. Crystal Structure and Molecular Conformation of Tetraamine(methylenephosphato)-cobalt(III) Hydrochloride (CoPCP): CoH2P2O6CH2(NH3)4+ .Cl-. T. P. Haromy, W. B. Knight, D. Dunaway-Mariano* and M. Sundaralingam*, Inorg. Chem. 23: 2412 (1984).

23. Preparation and Characterization of Co(III) and Cr(III) Complexes of Adenosine 5'-diphosphate. I. Lin., A. Hseuh and D. Dunaway-Mariano*, Inorganic Chemistry 23: 1692 (1984).

24. Stereospecific Synthesis of P1,P2-Bidentate Co(NH3) (thiopyrophosphate) and P1,P2-Bidentate Cr(H2O)4(thiopyrophosphate) Enantiomers. I. Lin and D. Dunaway-Mariano*, J. Amer. Chem. Soc. 106: 6074 (1984).

25. Recent Advances in the Use of Exchange Inert Complexes of Nucleotides with Cr(III), Co(III) and Rh(III) as Stereochemical Probes. D. Dunaway-Mariano*, Stereochemistry of Enzymatic Reactions. Ed. P. Frey, Elsevier Science Publ. Co. N. Y., N. Y. pp. 149-164 (1985).

26. Investigation of the Regiospecificity and Stereospecificity of Proton Transfer in the Yeast Inorganic Pyrophosphatase Catalyzed Reaction. I. Lin, W. B. Knight, A. Hseuh and D. Dunaway-Mariano*, Biochemistry 25: 4688 (1986).

27. Inhibition and Inactivation of Pyruvate Phosphate Dikinase with Cr(III) Complexes of ATP and PP. L. Ciskanik, and D. Dunaway-Mariano*, J. Enzyme Inhibition 1: 113 (1986).

28. The Kinetic Mechanism of Yeast Inorganic Pyrophosphatase. R. J. Barry and Debra Dunaway-Mariano*. Archives of Biochemistry and Biophysics 259:196 (1987).

29. Structural and Biochemical Properties of Bidentate Tetraaqua Rh(III) Complexes of Inorganic Pyrophosphate and Adenosine 5'-Diphosphate. A. L. Shorter, T. P. Haromy, T. Scalzo-Brush, W. B. Knight, D. Dunaway-Mariano* and M. S. Sundaralingam, Biochemistry 25: 2060 (1987).

30. Synthesis and Stereochemical Analysis of exchange Inert Cr(III) Complexes of Adenosine-5'-O-(2-thiodiphosphate) Adenosine-5'-O-(2-thiotriphosphate) and Adenosine-5'-O-(3-thiotriphosphate). Generation of a New Class of Chiral Enzyme Active Site Probes. I. Lin and D. Dunaway-Mariano*, J. Amer. Chem. Soc. 110: 950 (1988).

31. Preparation and configurational analysis of the stereoisomers of b,g-bidentate Rh(H2O)4ATP and a,b,g-tridentate Rh(H2O)3ATP.  A new class of enzyme active site probes.  Lu, Zichun; Shorter, Andrew L.; Lin, Irene; Dunaway-Mariano, Debra.  Inorganic Chemistry  27(23):  4135-9 (1988).

32. Investigations of the Partial Reactions Catalyzed by Pyruvate Phosphate Dikinase from Bacteriodes Symbiosus. H.-C. Wang, L. Ciskanik, W. VonderSaal, J. J. Villafranca and D. Dunaway-Mariano*, Biochemistry 27: 625 (1988).

33. Investigation of the Bacillus cereus Phosphonoacetaldehyde Hydrolase. Evidence for a Schiff Base Mechanism and Sequence Analysis of an Active Site Peptide Containing the Catalytic Lysine Residue. D. B. Olsen, T. W. Hepburn, M. Moos, P. S. Mariano and D. Dunaway-Mariano*, Biochemistry 27: 2229 (1988).

34. Elucidation of the 2-Aminoethylphosphonate Biosynthetic Pathway in Tetrahymena pyriformis. R. Barry, E. Bowman, M. McQueney and D. Dunaway-Mariano*, Biochem. and Biophys. Res. Comm.. 153: 177 (1988).

35. Catalysis and Thermodynamics of the Rearrangement of Phosphoenol Pyruvate to Phosphonopyruvate. Entry into the Phosphonate Class of Naturally Occurring Organophosphonates. E. Bowman, M. McQueney, R. Barry and D. Dunaway-Mariano*, J. Amer. Chem.Soc., 110: 5575 (1988).

36. Investigation of the Substrate Structure and Metal Cofactor Requirements of the Rat Liver Mitochondrial Proton Pump ATPase. S. Hanley-Trawick, M. E. Carpen, P. L. Pedersen, J. Hulliken and D. Dunaway-Mariano*, Archives of Biochemistry and Biophysics, 268: 116 (1989).

37. The mode of triple phosphoryl group transfer in pyruvate phosphate dikinase catalysis.  Demonstration of the intermediacy of pyrophosphorylated and phosphorylated enzyme species.  Carroll, Lawrence J.; Mehl, Andrew F.; Dunaway-Mariano, Debra.  Journal of the American Chemical Society  111(15):  5965-7. (1989)

38. A Remarkable Pericyclic Mechanism for Enzyme-Catalyzed P-C Bond Formation. M. S. McQueney, S.-L. Lee, E. Bowman, P. S. Mariano and D. Dunaway-Mariano, J. Amer. Chem. Soc., 111: 6885 (1989).

39. Purification and Characterization of the Tetrahymena Pyriformis P-C Bond Forming Enzyme, Phosphoenol Pyruvate Phosphomutase. E. D. Bowman, M. S. McQueney, J. D. Scholten and D. Dunaway-Mariano*, Biochemistry. 29: 7059 (1990).

40. A Method for Chiral Thiophosphonate Synthesis and its Use in Elucidating the Phosphorus Stereochemistry of the Hydrolytic C-P Bond Cleavage Reaction of Thiophosphono-acetaldehyde. S. L. Lee, T. W. Hepburn, P. S. Mariano* and D. Dunaway-Mariano*, J. Organic Chem., 55: 5435 (1990).

41. Determination of the Catalytic Pathway of C4-Leaf Pyruvate Orthophosphate Dikinase from Maize. L. J. Carroll, D. Dunaway-Mariano*, C. M. Smith and R. Chollett, FEBS Lett., 274: 178 (1990).

42. Analysis of Sequence Homologies in Plant and Bacterial Pyruvate Phosphate Dikinase, Enzyme I of Bacterial Phosphoenolpyruvate: Sugar Phosphotransferase System and Other PEP-Utilizing Enzymes: Identification of Potential Catalytic and Regulatory Motifs. D. J. Pocalyko, L. J. Carroll, B. M. Martin, P. C. Babbitt and Debra Dunaway-Mariano*, Biochemistry, 29: 10757 (1990).

For the research publications after 1990, please click this link: 1991-2000.